Mixed-ligand complexes of paddlewheel dinuclear molybdenum as hydrodehalogenation catalysts for polyhaloalkanes
نویسندگان
چکیده
منابع مشابه
Dissymmetric dinuclear transition metal complexes as dual site catalysts for the polymerization of ethylene
A series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization, by coupling the allylated a-diimine complexes of the metals Ti, Zr, V, Ni and Pd with the ansa-zirconocene complex [C5H4-SiH(Me)-C5H4]ZrCl2 possessing a hydride silane moiety. The different stages of syntheses included the formation of bis(cyclopentadienide)methyl silane which was u...
متن کاملMixed-ligand complexes of paddlewheel dinuclear molybdenum as hydrodehalogenation catalysts for polyhaloalkanes† †Electronic supplementary information (ESI) available: Experimental details for the synthesis and characterization of Mo2 complexes, kinetic analysis of the reactions, 1H NMR spectra of the catalytic reactions, identification of the products, CV of selected Mo2 complexes, and crystal data for 7a (CCDC 1046579), 9a (CCDC 1046580), 10a (CCDC 1046581), and 11a (CCDC 1046582). CCDC 1046579–1046582. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00721f
متن کامل
dissymmetric dinuclear transition metal complexes as dual site catalysts for the polymerization of ethylene
a series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization,by coupling the allylated a-diimine complexes of the metals ti, zr, v, ni and pd with the ansa-zirconocenecomplex [c5h4-sih(me)-c5h4]zrcl2 possessing a hydride silane moiety. the different stages of syntheses includedthe formation of bis(cyclopentadienide)methyl silane which was util...
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The synthesis, spectroscopy and magnetic characterization of five new dinuclear copper(II) complexes are described. All five compounds have the general formula [Cu2(L)4(O-R)2](Cl)2 or [Cu2(L)2(Cl)2](Cl)2, in which R = CH3 or H, L=2, 3 or 4-pyridinemethanol as L2, L3 or L4, respectively. The title compounds consist of dinuclear units with bridging methoxo groups in [Cu2(L4)4(O-CH3)2](Cl)2, hydro...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c5sc00721f